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The end-Frasnian extinction (the largest) about 375 million years ago.

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Archeozoic: end of Azoic to 2,500,000,000 years ago: The era of the earliest living beings on earth.

It is suggested that analysis of sedimentary pyrite from the Belingwe sedimentary basin in Zimbabwe may provide evidence for bacterial reduction at this date.

2,500,000,000 to 542,000,000 years ago The Proterozoic Eon: the most recent part of the Precambrian Supereon.

By carboniferous [carbon bearing] soils, Richard Kirwan in 1799 meant the "various sorts of earth or stone among or under which coal is usually found".

William Daniel Conybeare and William Phillips (1822, page vii) proposed to consider all rocks in an ascending order with a group including "not only the great coal-deposit itself, but those of the limestone and sandstone also on which it reposes" as the "medial" [middle] order.